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Spider-Man's wall crawling abilities have been explained in several ways. Some notable explanations include:
A panel of biologists and physicists on the History Channel’s Spider-Man Tech suggested the barbed-hair on his fingertips (from the movie) could have the same effect as the miniature scopulae hairs on the ends of a spider’s feet. Spiders are able to climb up seemingly impossible surfaces like glass because the scopulae interact with the glass’s atoms causing a form of atomic static cling via the Van der Waals force.